Guest-Adaptable Spin Crossover Properties Underpinned by Supramolecular Interactions
Physical Sciences, Massey University
Time & Place
Wed, 07 Nov 2018 12:00:00 NZDT in Room 701, Level 7, West Building
All are welcome
Porous materials, such as metal-organic frameworks or coordination polymers, are often investigated for their ability to adsorb molecular guests. In many cases, uptake is concomitant with changes to physical properties, allowing for their modulation via guest adsortption. Somewhat counter-intuitively, discrete molecular materials that are often nonporous can also act in this way, provided that a network of supramolecular interactions is present and capable of supporting the crystal lattice during guest removal. Herein, we explore the role of these supramolecular interactions for a series of dinuclear complexes, determining their role in affecting substantial changes to structural-magnetic switching properties in response to guest removal.