Qualifications & Memberships
Our research interests touch upon all aspects of supramolecular chemistry ranging from organic synthesis and coordination chemistry, through materials and structural chemistry, to host-guest and sensor chemistry. This work is underpinned by structural analysis by single-crystal X-ray diffraction which is complimented by a range of spectroscopic techniques.
Our research into coordination polymers and porous metal-organic frameworks involves transition and lanthanide metal ions and poly-carboxylate-poly-pyridine ligands. We are also interested in the coordination chemistry of clusters as structural and functional bio-models and their potential to behave as single molecule magnets.
Our work in Supramolecular Chemistry ranges from anion coordination chemistry and sensing, involving the development of naked-eye sensors for anions in aqueous media; to the supramolecular coordination chemistry of helical complexes, incorporating metallo- helicate synthesis and anion directed synthesis of helical species. Recent work looks to marry Fe(II)-based spin-crossover (SCO) phenomena into helicate systems in an attempt to form sensor molecules who output derives from SCO associated colour changes.
- Preston D. and Kruger PE. (2019) Reversible Transformation between a [PdL2 ]2+ "Figure-of-Eight" Complex and a [Pd2 L2 ]4+ Dimer: Switching On and Off Self-Recognition.. Chemistry 25(7): 1781-1786. http://dx.doi.org/10.1002/chem.201805172.
- Archer RJ., Scott HS., Polson MIJ., Williamson BE., Mathonière C., Rouzières M., Clérac R. and Kruger PE. (2018) Varied spin crossover behaviour in a family of dinuclear Fe(ii) triple helicate complexes.. Dalton Trans 47(24): 7965-7974. http://dx.doi.org/10.1039/c8dt01567h.
- Morshedi M., Ward JS., Kruger PE. and White NG. (2018) Supramolecular frameworks based on 5,10,15,20-tetra(4-carboxyphenyl)porphyrins.. Dalton Trans 47(3): 783-790. http://dx.doi.org/10.1039/c7dt04162d.
- Scott HS., Mukherjee S., Turner DR., Polson MIJ., Zaworotko MJ. and Kruger PE. (2018) Crystal engineering of dichromate pillared hybrid ultramicroporous materials incorporating pyrazole-based ligands. CRYSTENGCOMM 20(9): 1193-1197. http://dx.doi.org/10.1039/c8ce00149a.
- Scott HS., Staniland RW. and Kruger PE. (2018) Spin crossover in homoleptic Fe(II) imidazolylimine complexes. COORDINATION CHEMISTRY REVIEWS 362: 24-43. http://dx.doi.org/10.1016/j.ccr.2018.02.001.